Frantisek Hartl

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+44 (0) 118 378 7695
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Professor
- Professor of Inorganic Chemistry
- Head of Spectroelectrochemistry.
Office
118Building location
ChemistryAreas of interest
- Spectroelectrochemistry – application and development of new cells
- Unusual oxidation states of organometallic compounds
- Photoinduced electron and energy transfer
- Molecular wires
- Photo- and redox catalysis
- Activation of carbon dioxide via proton coupled electron transfer.
Read about spectroelectrochemistry
Research centres and groups
Professor Hartl is part of the Biomedical, Molecular and Analytical Chemistry research group.Learn more about our research groups
Publications
- Hartl, F. and Taylor, J. (2020) Strong impact of intramolecular hydrogen bonding on the cathodic path of [Re(CO)3(3,3’-dihydroxy-2,2’-bipyridine)Cl] and catalytic reduction of carbon dioxide. Inorganic Chemistry , 59 (8). pp. 5564-5578. ISSN: 0020-1669 | doi: http://dx.doi.org/10.1021/acs.inorgchem.0c00263
- Hartl, F. , Hu, Y. , Zhang, J. , Zhang, F. , Wang, X. , Jun, Y. , Liu, S. (2020) Electronic properties of oxidized cyclometalated diiridium complexes: spin delocalization controlled by the mutual position of the iridium centres. Chemistry- A European Journal , 26 (20). pp. 4567-4575. ISSN: 1521-3765 | doi: http://dx.doi.org/10.1002/chem.201904894
- Hartl, F. , Taylor, J. , Wang, Y. (2020) Photo-assisted electrocatalytic reduction of CO2: A new strategy for reducing catalytic overpotentials. ChemCatChem , 12 (1). pp. 386-393. ISSN: 1867-3899 | doi: http://dx.doi.org/10.1002/cctc.201901887
- Keane, P. , Tory, J. , Towrie, M. , Sazanowich, I. , Cardin, C. , Quinn, S. , Hartl, F. , Kelly, J. , Long, C. (2019) Spectro-electrochemical studies on [Ru(TAP)2(dppz)]2+ - insights into the mechanism of its photosensitized oxidation of oligonucleotides. Inorganic Chemistry , 58 (1). pp. 663-671. ISSN: 0020-1669 | doi: http://dx.doi.org/10.1021/acs.inorgchem.8b02859
- Taylor, J. , Veenstra, F. , Chippindale, A. , Calhorda, M. , Hartl, F. (2019) Group 6 metal complexes as electrocatalysts of CO2 reduction: strong substituent control of the reduction path of [Mo(η3-allyl)(CO)2(x,x′-dimethyl-2,2′-bipyridine)(NCS)] (x = 4–6). Organometallics , 38 (6). pp. 1372-1390. ISSN: 1520-6041 | doi: http://dx.doi.org/10.1021/acs.organomet.8b00676
- Taylor, J. , Veenstra, F. , Chippindale, A. , Calhorda, M. , Hartl, F. (2019) Group 6 complexes as electrocatalysts of CO2 reduction: strong substituent control of the reduction path of [Mo(η3-allyl)(CO)2(x,x′- dimethyl-2,2′-bipyridine)(NCS)] (x = 4-6). Organometallics , 38 (6). pp. 1372-1390. ISSN: 1520-6041 | doi: http://dx.doi.org/10.1021/acs.organomet.8b00676
- Ryan, D. and Hartl, F. (2018) IR Spectro-electrochemistry and group-6 alpha-diimine catalysts of CO2 reduction. In: Marken, F. and Fermin, D. , (eds.) Electrochemical Reduction of Carbon Dioxide: Overcoming the Limitations of Photosynthesis. Energy & Environment Royal Society of Chemistry pp. 182-211. ISBN: 9781782620426 | doi: http://dx.doi.org/10.1039/9781782623809
- Zhang, M. , Zhang, J. , Jin, X. , Sun, X. , Yin, J. , Hartl, F. , Liu, S. (2018) Diphenylamine-substituted osmanaphthalyne complexes: structural, bonding, and redox properties of unusual donor–bridge–acceptor systems. Chemistry - A European Journal , 24 (71). pp. 18998-19009. ISSN: 0947-6539 | doi: http://dx.doi.org/10.1002/chem.201804025
- Hartl, F. , Bakker, M. , Santos, V. , Costa, P. , Calhorda, M. (2018) Accurate description of low-lying excited states in a series of photoreactive clusters [Os3(CO)10(α-diimine)] by DFT calculations. Inorganic Chemistry , 57 (18). pp. 11704-11716. ISSN: 0020-1669 | doi: http://dx.doi.org/10.1021/acs.inorgchem.8b01847
- Zhang, M. , Zhang, J. , Yin, J. , Hartl, F. , Liu, S. (2018) Anodic electrochemistry of mono- and dinuclear aminophenylferrocene and diphenylaminoferrocene complexes. Dalton Transactions , 47 (17). pp. 6112-6123. ISSN: 1364-5447 | doi: http://dx.doi.org/10.1039/c8dt00584b
- Taylor, J. , Leavey, R. , Hartl, F. (2018) Solvent and ligand substitution effects on electrocatalytic reduction of CO2 with [Mo(CO)4(x,xʹ-dimethyl-2,2′-bipyridine)] (x = 4-6) enhanced at a gold cathodic surface. ChemElectroChem , 5 (21). pp. 3155-3161. ISSN: 2196-0216 | doi: http://dx.doi.org/10.1002/celc.201800879
- Herrmann, D. , Rödl, C. , de Bruin, B. , Hartl, F. , Wolf, R. (2018) Synthesis, electronic structure and redox properties of the diruthenium sandwich complexes [Cp*Ru(μ-C10H8)RuCp*]x (x = 0, 1+; Cp* = C5Me5; C10H8 = naphthalene). Dalton Transactions , 47 (32). pp. 11058-11069. ISSN: 1477-9226 | doi: http://dx.doi.org/10.1039/c8dt02003e
- Strudwick, B. , Zhang, J. , Hilbers, M. , Buma, W. , Woutersen, S. , Liu, S. , Hartl, F. (2018) Excited-state electronic asymmetry prevents photoswitching in terthiophene compounds. Inorganic Chemistry , 57 (15). pp. 9039-9047. ISSN: 0020-1669 | doi: http://dx.doi.org/10.1021/acs.inorgchem.8b01005
- Chen, L. , Lim, K. , Babra, T. , Taylor, J. , Pižl, M. , Evans, R. , Chippindale, A. , Hartl, F. , Colquhoun, H. , Greenland, B. (2018) A macrocyclic receptor containing two viologen species connected by conjugated terphenyl groups. Organic & Biomolecular Chemistry , 16 (27). pp. 5006-5015. ISSN: 1477-0520 | doi: http://dx.doi.org/10.1039/c8ob00919h
- Chen, L. , Vivier, E. , Eling, C. , Babra, T. , Bouillard, J. , Adawi, A. , Benoit, D. , Hartl, F. , Colquhoun, H. , Efremova, O. , Greenland, B. (2018) Conjugated, rod-like viologen oligomers: correlation of oligomer length with conductivity and photoconductivity. Synthetic Metals , 241 pp. 31-38. ISSN: 0379-6779 | doi: http://dx.doi.org/10.1016/j.synthmet.2018.03.019
- Biswas, S. , Ma, S. , Nuzzo, S. , Twamley, B. , Russell, A. , Platts, J. , Hartl, F. , Baker, R. (2017) Structural variability of 4f and 5f thiocyanate complexes and dissociation of uranium(III)–thiocyanate bonds with increased ionicity. Inorganic Chemistry , 56 (23). pp. 14426-14437. ISSN: 1520-510X | doi: http://dx.doi.org/10.1021/acs.inorgchem.7b01560
- Ou, Y. , Zhang, J. , Zhang, M. , Zhang, F. , Kuang, D. , Hartl, F. , Liu, S. (2017) Bonding and electronic properties of linear diethynyl oligothienoacene-bridged diruthenium complexes and their oxidized forms. Inorganic Chemistry , 56 (18). pp. 11074-11086. ISSN: 0020-1669 | doi: http://dx.doi.org/10.1021/acs.inorgchem.7b01433
- Wang, D. , Capel Ferrón, C. , Li, J. , Gámez-Valenzuela, S. , Ponce Ortiz, R. , López Navarrete, J. , Hernández Jolín, V. , Yang, X. , Peña Álvarez, M. , García Baonza, V. , Hartl, F. , Ruiz Delgado, M. , Li, H. (2017) New multiresponsive chromic soft materials: dynamic interconversion of short 2,7-dicyanomethylenecarbazole-based biradicaloid and the corresponding cyclophane tetramer. Chemistry- A European Journal , 23 (55). pp. 13776-13783. ISSN: 1521-3765 | doi: http://dx.doi.org/10.1002/chem.201702659
- Chen, L. , Hartl, F. , Colquhoun, H. , Greenland, B. (2017) Prediction of cathodic E1/2 1 and E1/2 2 values for viologen-containing conjugated unimers and dimers from calculated pKb values of the aromatic substituents. Tetrahedron Letters , 58 (19). pp. 1859-1862. ISSN: 0040-4039 | doi: http://dx.doi.org/10.1016/j.tetlet.2017.03.089
- Vincent, K. , Gluyas, J. , Zeng, Q. , Yufit, D. , Howard, J. , Hartl, F. , Low, P. (2017) Sandwich and half-sandwich metal complexes derived from cross-conjugated 3-methylene-penta-1,4-diynes. Dalton Transactions , 46 (17). pp. 5522-5531. ISSN: 1364-5447 | doi: http://dx.doi.org/10.1039/c6dt04470k
- Ryan, D. , Cardin, D. , Hartl, F. (2017) η3-Allyl carbonyl complexes of group 6 metals: structural aspects, isomerism, dynamic behaviour and reactivity. Coordination Chemistry Reviews , 335 pp. 103-149. ISSN: 0010-8545 | doi: http://dx.doi.org/10.1016/j.ccr.2016.12.018
- Zhang, J. , Guo, S. , Don, Y. , Rao, L. , Jin, Y. , Yu, G. , Hartl, F. , Liu, S. (2017) Multistep oxidation of diethynyl oligophenylamine-bridged diruthenium and diiron complexes. Inorganic Chemistry , 56 (2). pp. 1001-1015. ISSN: 0020-1669 | doi: http://dx.doi.org/10.1021/acs.inorgchem.6b02809
- Wu, H. , Fang, R. , Tao, J. , Wang, D. , Qiao, X. , Yang, X. , Hartl, F. , Li, H. (2017) Diacenaphthylene-fused benzo[1,2-b:4,5-b‘]dithiophenes: polycyclic heteroacenes containing full-carbon five-membered aromatic rings. Chemical Communications , 53 (4). pp. 751-754. ISSN: 1364-548X | doi: http://dx.doi.org/10.1039/C6CC09184A
- Ou, Y. , Zhang, J. , Kuang, D. , Zhang, F. , Yu, J. , Zhu, X. , Liu, S. , Hartl, F. (2017) Mononuclear piano-stool iron 2-ethynylbenzo[b]thiophene complex: crystal structure and reversible oxidation studied by spectro-electrochemical and DFT methods. Journal of Coordination Chemistry , 70 (4). pp. 722-733. ISSN: 0095-8972 | doi: http://dx.doi.org/10.1080/00958972.2016.1278434
- Vincent, K. , Gluyas, J. , Guckel, S. , Zeng, Q. , Hartl, F. , Kaupp, M. , Low, P. (2016) Tetrakis(ferrocenylethynyl)ethene:synthesis, spectro)electrochemical and quantum chemical characterisation. Journal of Organometallic Chemistry , 821 pp. 40-47. ISSN: 0022-328X | doi: http://dx.doi.org/10.1016/j.jorganchem.2016.04.018
- Spall, S. , Keane, T. , Tory, J. , Cocker, D. , Adams, H. , Fowler, H. , Meijer, A. , Hartl, F. , Weinstein, J. (2016) Manganese tricarbonyl complexes with asymmetric 2 2‑iminopyridine ligands: toward decoupling steric and electronic 3 factors in electrocatalytic CO2 reduction. Inorganic Chemistry , 55 (24). pp. 12568-12582. ISSN: 0020-1669 | doi: http://dx.doi.org/10.1021/acs.inorgchem.6b01477
- Broere, D. , Plessius, R. , Tory, J. , Demeshko, S. , de Bruin, B. , Siegler, M. , Hartl, F. , van der Vlugt, J. (2016) Localized mixed-valence and redox activity within a triazole-bridged dinucleating ligand upon coordination to palladium. Chemistry- A European Journal , 22 (39). pp. 13965-13975. ISSN: 1521-3765 | doi: http://dx.doi.org/10.1002/chem.201601900
- Davidson, R. , Al-Owaedi, O. , Milan, D. , Zeng, Q. , Tory, J. , Hartl, F. , Higgins, S. , Nichols, R. , Lambert, C. , Low, P. (2016) Effects of electrode−molecule binding and junction geometry on the single-molecule conductance of bis-2,2′:6′,2″-terpyridine-based complexes. Inorganic Chemistry , 55 (6). pp. 2691-2700. ISSN: 1520-510X | doi: http://dx.doi.org/10.1021/acs.inorgchem.5b02094
- Ou, Y. , Zhang, J. , Zhang, F. , Kuang, D. , Hartl, F. , Rao, L. , Liu, S. (2016) Notable differences between oxidized diruthenium complexes bridged by four isomeric diethynyl benzodithiophene ligands. Dalton Transactions , 45 (15). pp. 6503-6516. ISSN: 1364-5447 | doi: http://dx.doi.org/10.1039/c6dt00109b
- Zhang, J. , Sun, C. , Zhang, M. , Hartl, F. , Yin, J. , Yu, G. , Rao, L. , Liu, S. (2016) Asymmetric oxidation of vinyl- and ethynyl terthiophene ligands in triruthenium complexes. Dalton Transactions , 45 (2). pp. 768-782. ISSN: 1364-5447 | doi: http://dx.doi.org/10.1039/c5dt04083c
- Chen, L. , Willcock, H. , Wedge, C. , Hartl, F. , Colquhoun, H. , Greenland, B. (2016) Efficient access to conjugated 4,4’-bipyridinium oligomers using the Zincke reaction: synthesis, spectroscopic and electrochemical properties. Organic and Biomolecular Chemistry , 14 (3). pp. 980-988. ISSN: 1477-0520 | doi: http://dx.doi.org/10.1039/c5ob02211h
- Osorio, H. , Catarelli, S. , Cea, P. , Gluyas, J. , Hartl, F. , Higgins, S. , Leary, E. , Low, P. , Martín, S. , Nichols, R. , Tory, J. , Ulstrup, J. , Vezzoli, A. , Milan, D. , Zeng, Q. (2015) Electrochemical single-molecule transistors with optimized gate coupling. Journal of the American Chemical Society , 137 (45). pp. 14319-14328. ISSN: 0002-7863 | doi: http://dx.doi.org/10.1021/jacs.5b08431
- Zeng, Q. , Lewis, F. , Harwood, L. , Hartl, F. (2015) Role of ligands in catalytic water oxidation by mononuclear ruthenium complexes. Coordination Chemistry Reviews , 304-305 pp. 88-101. ISSN: 0010-8545 | doi: http://dx.doi.org/10.1016/j.ccr.2015.03.003
- Zhang, J. , Zhang, M. , Sun, C. , Xu, M. , Hartl, F. , Yin, J. , Yu, G. , Rao, L. , Liu, S. (2015) Diruthenium complexes with bridging diethynyl polyaromatic ligands: synthesis, spectroelectrochemistry, and theoretical calculations. Organometallics , 34 (16). pp. 3967-3978. ISSN: 1520-6041 | doi: http://dx.doi.org/10.1021/acs.organomet.5b00276
- Domingos, S. , Hartl, F. , Buma, W. , Woutersen, S. (2015) Elucidating the structure of chiral molecules by using amplified vibrational circular dichroism: from theory to experimental realization. ChemPhysChem , 16 (16). pp. 3363-3373. ISSN: 1439-7641 | doi: http://dx.doi.org/10.1002/cphc.201500551
- Tory, J. , Setterfield-Price, B. , Dryfe, R. , Hartl, F. (2015) [M(CO)4(2,2′-bipyridine)] (M = Cr, Mo, W) as efficient catalysts for electrochemical reduction of CO2 to CO at a gold electrode. ChemElectroChem , 2 (2). pp. 213-217. ISSN: 2196-0216 | doi: http://dx.doi.org/10.1002/celc.201402282
- Domingos, S. , Sanders, H. , Hartl, F. , Buma, W. , Woutersen, S. (2014) Switchable amplification of vibrational circular dichroism as a probe of local chiral structure. Angewandte Chemie-International Edition , 53 (51). pp. 14042-14045. ISSN: 1521-3773 | doi: http://dx.doi.org/10.1002/anie.201407376
- Bubrin, M. , Schweinfurth, D. , Ehret, F. , Záliš, S. , Kvapilová, H. , Fiedler, J. , Zeng, Q. , Hartl, F. , Kaim, W. (2014) Structure and spectroelectrochemical response of arene− ruthenium and arene−osmium complexes with potentially hemilabile noninnocent ligands. Organometallics , 33 (18). pp. 4973-4985. ISSN: 1520-6041 | doi: http://dx.doi.org/10.1021/om5002815
- Zeng, Q. , Tory, J. , Hartl, F. (2014) Electrocatalytic reduction of carbon dioxide with a manganese(I)tricarbonyl complex containing a nonaromatic α‑diimine ligand. Organometallics , 33 (18). pp. 5002-5008. ISSN: 1520-6041 | doi: http://dx.doi.org/10.1021/om500389y
- Hashem, E. , Platts, J. , Hartl, F. , Lorusso, G. , Evangelisti, M. , Schulzke, C. , Baker, R. (2014) Thiocyanate complexes of uranium in multiple oxidation states: a combined structural, magnetic, spectroscopic, spectroelectrochemical, and theoretical study. Inorganic Chemistry , 53 (16). pp. 8624-8637. ISSN: 0020-1669 | doi: http://dx.doi.org/10.1021/ic501236j
- Ferrón, C. , Capdevila-Cortada, M. , Balster, R. , Hartl, F. , Niu, W. , He, M. , Novoa, J. , Navarrete, J. , Hernández, V. , Delgado, M. (2014) Multistep π dimerization of tetrakis(n-decyl)heptathienoacene radical cations: a combined experimental and theoretical study. Chemistry- A European Journal , 20 (33). pp. 10351-10359. ISSN: 1521-3765 | doi: http://dx.doi.org/10.1002/chem.201402182
- Li, P. , Amirjalayer, S. , Hartl, F. , Lutz, M. , de Bruin, B. , Becker, R. , Woutersen, S. , Reek, J. (2014) Direct probing of photoinduced electron transfer in a self- assembled biomimetic [2Fe2S]-hydrogenase complex using ultrafast vibrational spectroscopy. Inorganic Chemistry , 53 (10). pp. 5373-5383. ISSN: 0020-1669 | doi: http://dx.doi.org/10.1021/ic500777d
- Ou, Y. , Zhang, J. , Xu, M. , Xia, J. , Hartl, F. , Yin, J. , Yu, G. , Liu, S. (2014) Bridge-localized HOMO-binding character of divinylanthracene-bridged dinuclear ruthenium carbonyl complexes: spectroscopic, spectroelectrochemical, and computational studies. Chemistry - An Asian Journal , 9 (4). pp. 1152-1160. ISSN: 1861-471X | doi: http://dx.doi.org/10.1002/asia.201301544
- Pelties, S. , Herrmann, D. , de Bruin, B. , Hartl, F. , Wolf, R. (2014) Selective P4 activation by an organometallic nickel(I) radical: formation of a dinuclear nickel(II) tetraphosphide and related di- and trichalcogenides. Chemical Communications , 50 (53). pp. 7014-7016. ISSN: 1359-7345 | doi: http://dx.doi.org/10.1039/c4cc02601b
- Derossi, S. , Becker, R. , Li, P. , Hartl, F. , Reek, J. (2014) A phosphoramidite-based [FeFe]H2ase functional mimic displaying fast electrocatalytic proton reduction. Dalton Transactions , 43 (22). pp. 8363-8367. ISSN: 1364-5447 | doi: http://dx.doi.org/10.1039/c3dt53471e
- Tory, J. , Gobaille-Shaw, G. , Chippindale, A. , Hartl, F. (2014) Spectroelectrochemical study of complexes [Mo(CO)2(h3-allyl)(adiimine)(NCS)] (a-diimine ¼ bis(2,6-dimethylphenyl)- acenaphthenequinonediimine and 2,20-bipyridine) exhibiting different molecular structure and redox reactivity. Journal of Organometallic Chemistry , 760 pp. 30-40. ISSN: 0022-328X | doi: http://dx.doi.org/10.1016/j.jorganchem.2014.01.015
- Tory, J. , King, L. , Maroulis, A. , Haukka, M. , Calhorda, M. , Hartl, F. (2014) Solvent-Dependent Formation of Os(0) Complexes by Electrochemical Reduction of [Os(CO)(2,2′-bipyridine)(L)Cl2]; L = Cl−,PrCN. Inorganic Chemistry , 53 (3). pp. 1382-1396. ISSN: 0020-1669 | doi: http://dx.doi.org/10.1021/ic402146t
- Grupp, A. , Bubrin, M. , Ehret, F. , Zeng, Q. , Hartl, F. , Kvapilová, H. , Zálisˇ, S. , Kaim, W. (2013) RuII(α-diimine) or RuIII(α-diimine·–)? Structural, spectroscopic, and theoretical evidence for the stabilization of a prominent metal-to-Ligand charge- transfer excited-state configuration in the ground state. European Journal of Inorganic Chemistry , 2014 (1). pp. 110-119. ISSN: 1434-1948 | doi: http://dx.doi.org/10.1002/ejic.201301206
- Portius, P. , Davis, M. , Campbell, R. , Hartl, F. , Zeng, Q. , Meijer, A. , Towrie, M. (2013) Dinitrogen release from arylpentazole: A picosecond time-resolved infrared, spectroelectrochemical, and DFT computational study. Journal of Physical Chemistry A , 117 (48). pp. 12759-12769. ISSN: 1089-5639 | doi: http://dx.doi.org/10.1021/jp4077454
- Vincent, K. , Zeng, Q. , Parthey, M. , Yufit, D. , Howard, J. , Hartl, F. , Kaupp, M. , Low, P. (2013) Syntheses, spectroelectrochemical studies, and molecular and electronic structures of ferrocenyl ene-diynes. Organometallics , 32 (20). pp. 6022-6032. ISSN: 1520-6041 | doi: http://dx.doi.org/10.1021/om400535y
- Malberg, J. , Lupton, E. , Schnöckelborg, E. , de Bruin, B. , Sutter, J. , Meyer, K. , Hartl, F. , Wolf, R. (2013) Synthesis and Electronic Structure of Dissymmetrical, Naphthalene-Bridged Sandwich Complexes [Cp′Fe(μ‑C10H8)MCp*]x (x = 0, +1; M =Fe, Ru; Cp′ = η5‑C5H2‑1,2,4‑tBu3; Cp* = η5‑C5Me5). Organometallics , 32 (20). pp. 6040-6052. ISSN: 1520-6041 | doi: http://dx.doi.org/10.1021/om4005862
- Rizalman, N. , Ferron, C. , Niu, W. , Wallace, A. , He, M. , Balster, R. , Lampkin, J. , Hernandez, V. , Lopez, J. , Delgado, M. , Hartl, F. (2013) Radical cations of end-capped tetrathienoacenes and their p-dimerization controlled by the nature of a-substituents and counterion concentration. RSC Advances , 3 (48). pp. 25644-25647. ISSN: 2046-2069 | doi: http://dx.doi.org/10.1039/c3ra45899g
- Zeng, Q. , Messaoudani, M. , Vlcek Jr., A. , Hartl, F. (2013) Temperature-dependent reduction pathways of complexes fac-[Re(CO)3(N-R-imidazole)(1,10-phenanthroline)]+ (R = H, CH3). Electrochimica Acta , 110 pp. 702-708. ISSN: 0013-4686 | doi: http://dx.doi.org/10.1016/j.electacta.2013.02.018
- Domingos, S. , Luyten, H. , van Anrooij, F. , Sanders, H. , Bakker, B. , Buma, W. , Hartl, F. , Woutersen, S. (2013) An optically transparent thin-layer electrochemical cell for the study of vibrational circular dichroism of chiral redox-active molecules. Review of Scientific Instruments , 84 (3). ISSN: 0034-6748 | doi: http://dx.doi.org/10.1063/1.4793722
- Galangau, O. , Fabre-Francke, I. , Munteanu, S. , Dumas-Verdes, C. , Clavier, G. , Méallet-Renault, R. , Pansu, R. , Hartl, F. , Miomandre, F. (2013) Electrochromic and electrofluorochromic properties of a new boron dipyrromethene–ferrocene conjugate. Electrochimica Acta , 87 pp. 809-815. ISSN: 0013-4686 | doi: http://dx.doi.org/10.1016/j.electacta.2012.09.048
- Schnöckelborg, E. , Hartl, F. , Langer, T. , Pöttgen, R. , Wolf, R. (2012) Redox-active, dinuclear sandwich compounds [Cp*Fe(μ-L)FeCp*] (L = naphthalene and anthracene). European Journal of Inorganic Chemistry , 2012 (10). pp. 1632-1638. ISSN: 1099-0682 | doi: http://dx.doi.org/10.1002/ejic.201200001
- Zeng, Q. , Messaoudani, M. , Vlček, Jr., A. , Hartl, F. (2012) Electrochemical reductive deprotonation of an imidazole ligand in a bipyridine tricarbonyl rhenium(I) complex. European Journal of Inorganic Chemistry , 2012 (3). pp. 471-474. ISSN: 1099-0682 | doi: http://dx.doi.org/10.1002/ejic.201101100 (Special issue: Coopertive & redox non-innocent ligands in directing organometallic reactivity (cluster issue))
- Weymiens, W. , Hartl, F. , Lutz, M. , Slootweg, J. , Ehlers, A. , Mulder, J. , Lammertsma, K. (2012) Bis(azidophenyl)phosphole building block for extended π-conjugated systems. European Journal of Organic Chemistry , 2012 (34). pp. 6711-6721. ISSN: 1099-0690 | doi: http://dx.doi.org/10.1002/ejoc.201201148
- Chippindale, A. , Hibble, S. , Bilbe, E. , Marelli, E. , Hannon, A. , Allain, C. , Pansu, R. , Hartl, F. (2012) Mixed copper, silver, and gold cyanides, (MxM′1–x)CN: tailoring chain structures to influence physical properties. Journal of the American Chemical Society , 134 (39). pp. 16387-16400. ISSN: 0002-7863 | doi: http://dx.doi.org/10.1021/ja307087d
- Schnöckelborg, E. , Khusniyarov, M. , de Bruin, B. , Hartl, F. , Langer, T. , Eul, M. , Schulz, S. , Pöttgen, R. , Wolf, R. (2012) Unraveling the electronic structures of low-valent naphthalene and anthracene iron complexes: x-ray, spectroscopic, and density functional theory studies. Inorganic Chemistry , 51 (12). pp. 6719-6730. ISSN: 0020-1669 | doi: http://dx.doi.org/10.1021/ic300366m
- Wragg, A. , Derossi, S. , Easun, T. , George, M. , Sun, X. , Hartl, F. , Shelton, A. , Meijer, A. , Ward, M. (2012) Solvent-dependent modulation of metal–metal electronic interactions in a dinuclear cyanoruthenate complex: a detailed electrochemical, spectroscopic and computational study. Dalton Transactions , 41 (34). pp. 10354-10371. ISSN: 1364-5447 | doi: http://dx.doi.org/10.1039/c2dt31001e
- Domingos, S. , Panman , M. , Bakker, B. , Hartl, F. , Buma, W. , Woutersen, S. (2012) Amplifying vibrational circular dichroism by manipulation of the electronic manifold. Chemical Communications , 48 (3). pp. 353-355. ISSN: 1359-7345 | doi: http://dx.doi.org/10.1039/C1CC15369B
- Holzhacker, C. , Standfest-Hauser, C. , Puchberger, M. , Mereiter, K. , Veiros, L. , Calhorda, M. , Carvalho, M. , Ferreira, L. , Godinho, M. , Hartl, F. , Kirchner, K. (2011) Reversible addition of CO to coordinatively unsaturated high-spin iron(II) complexes. Organometallics , 30 (24). pp. 6587-6601. ISSN: 1520-6041 | doi: http://dx.doi.org/10.1021/om200711q
- Fox, M. , Guennic, B. , Roberts, R. , Brue, D. , Yufit, D. , Howard, J. , Manca, G. , Halet, J. , Hartl, F. , Low, P. (2011) Simultaneous bridge-localized and mixed-valence character in diruthenium radical cations featuring diethynylaromatic bridging ligands. Journal of the American Chemical Society , 133 (45). pp. 18433-18446. ISSN: 0002-7863 | doi: http://dx.doi.org/10.1021/ja207827m
- Ferron, C. , Delgado, M. , Hernandez, V. , Navarette, J. , Vercelli, B. , Zotti, G. , Cortada, M. , Novoa, J. , Niu, W. , He, M. , Hartl, F. (2011) Substituent and counterion effects on the formation of p-dimer dications of end-capped heptathienoacenes. Chemical Communications (47). pp. 12622-12624. ISSN: 1359-7345 | doi: http://dx.doi.org/10.1039/c1cc14566e
- Uma Maheswari, P. , Hartl, F. , Quesada, M. , Buda, F. , Lutz, M. , Spek, A. , Gamez, P. , Reedijk, J. (2011) Spectro-electrochemical and DFT studies of a planar Cu(II)–phenolate complex active in the aerobic oxidation of primary alcohols. Inorganica Chimica Acta , 374 (1). pp. 406-414. ISSN: 0020-1693 | doi: http://dx.doi.org/10.1016/j.ica.2011.03.029
- Záliš, S. , Consani, C. , El Nahhas, A. , Cannizzo, A. , Chergui, M. , Hartl, F. , Vlček, Jr, A. (2011) Origin of electronic absorption spectra of MLCT-excited and one-electron reduced 2,2′-bipyridine and 1,10-phenanthroline complexes. Inorganica Chimica Acta , 374 (1). pp. 578-585. ISSN: 0020-1693 | doi: http://dx.doi.org/10.1016/j.ica.2011.02.084
- Miomandre, F. , Allain, C. , Clavier, G. , Audibert, J. , Pansu, R. , Audebert, P. , Hartl, F. (2011) Coupling thin layer electrochemistry with epifluorescence microscopy: an expedient way of investigating electrofluorochromism of organic dyes. Electrochemistry Communications , 13 (6). pp. 574-577. ISSN: 1388-2481 | doi: http://dx.doi.org/10.1016/j.elecom.2011.03.013
- van het Goor, L. , van Duijnen, P. , Koper, C. , Jenneskens, L. , Havenith, R. , Hartl, F. (2010) π-dimerization of pleiadiene radical cations at low temperatures revealed by UV–vis spectroelectrochemistry and quantum theory. Journal of Solid State Electrochemistry , 15 (10). pp. 2107-2117. ISSN: 1433-0768 | doi: http://dx.doi.org/10.1007/s10008-011-1532-3
- Wolf, R. , Ehlers, A. , Khusniyarov, M. , Hartl, F. , de Bruin, B. , Long, G. , Grandjean, F. , Schappacher, F. , Pöttgen, R. , Slootweg, J. , Lutz, M. , Spek, A. , Lammertsma, K. (2010) Homoleptic Diphosphacyclobutadiene Complexes [M(η4-P2C2R2)2]x− (M=Fe, Co; x=0, 1). Chemistry - A European Journal , 16 (48). pp. 14322-14334. ISSN: 0947-6539 | doi: http://dx.doi.org/10.1002/chem.201001913
- Wolf, R. , Slootweg, J. , Ehlers, A. , Hartl, F. , de Bruin, B. , Lutz, M. , Spek, A. , Lammertsma, K. (2009) A phosphorus analogue of Bis(eta(4)-cyclobutadiene)iron(0) . Angewandte Chemie International Edition , 48 (17). pp. 3104-3107. ISSN: 1433-7851 | doi: http://dx.doi.org/10.1002/anie.200805193
- Wolf, . , Slootweg, . , Ehlers, . , Hartl, . , de Bruin, . , Lutz, . , Spek, . , Lammertsma, . (2009) A phosphorus analogue of Bis(eta(4)-cyclobutadiene)iron(0). Angewandte Chemie-International Edition , 48 (17). pp. 3104-3107. ISSN: 1433-7851 | doi: http://dx.doi.org/10.1002/anie.200805193
- Wadman, . , Lutz, . , Tooke, . , Spek, . , Hartl, . , Havenith, . , van Klink, . , van Koten, . (2009) Consequences of N,C,N '- and C,N,N '-coordination modes on electronic and photophysical properties of cyclometalated aryl ruthenium(II) complexes. Inorganic Chemistry , 48 (5). pp. 1887-1900. ISSN: 0020-1669 | doi: http://dx.doi.org/10.1021/ic801595m
- Wadman, . , Havenith, . , Hartl, . , Lutz, . , Spek, . , van Klink, . , van Koten, . (2009) Redox chemistry and electronic properties of 2,3,5,6-tetrakis(2-pyridyl)pyrazine-bridged diruthenium complexes controlled by N,C,N '-biscyclometalated ligands. Inorganic Chemistry , 48 (13). pp. 5685-5696. ISSN: 0020-1669 | doi: http://dx.doi.org/10.1021/ic801897k
- Tejel, . , del Rio, . , Ciriano, . , Reijerse, . , Hartl, . , Zalis, . , Hetterscheid, . , Spithas, . , de Bruin, . (2009) Ligand-centred reactivity of bis(picolyl)amine iridium: sequential deprotonation, oxidation and oxygenation of a "non-innocent" ligand. Chemistry- A European Journal , 15 (44). pp. 11878-11889. ISSN: 0947-6539 | doi: http://dx.doi.org/10.1002/chem.200901017
- Roy, S. , Maheswari, P. , Lutz, M. , Spek, A. , den Dulk, H. , Barends, S. , van Wezel, G. , Hartl, F. , Reedijk, J. (2009) DNA cleavage and antitumour activity of platinum(II) and copper(II) compounds derived from 4-methyl-2-N-(2-pyridylmethyl)aminophenol: spectroscopic, electrochemical and biological investigation. Dalton Transactions (48). pp. 10846-10860. ISSN: 1364-5447 | doi: http://dx.doi.org/10.1039/b911542k
- Kluwer, . , Kapre, . , Hartl, . , Lutz, . , Spek, . , Brouwer, . , van Leeuwen, . , Reek, . (2009) Self-assembled biomimetic [2Fe2S]-hydrogenase-based photocatalyst for molecular hydrogen evolution. Proceedings of the National Academy of Sciences of the USA , 106 (26). pp. 10460-10465. ISSN: 0027-8424 | doi: http://dx.doi.org/10.1073/pnas.0809666106
- Belser, . , De Cola, . , Hartl, . , Jukes, . , Bozic, . (2009) Photophysical and redox properties of dinuclear Ru and Os polypyridyl complexes with incorporated photostable spiropyran bridge. Inorganic Chemistry , 48 (4). pp. 1711-1721. ISSN: 0020-1669 | doi: http://dx.doi.org/10.1021/ic800963u
- Jukes, . , Kuhni, . , Salluce, . , Belser, . , De Cola, . , Hartl, . (2009) Photochemical, photophysical and redox properties of novel fulgimide derivatives with attached 2,2 '-bipyridine (bpy) and [M(bpy)(3)](2+) (M = Ru and Os) moieties. Dalton Transactions (20). pp. 3993-4002. ISSN: 1364-5447 | doi: http://dx.doi.org/10.1039/b821637c
- Hartl, . , Renfrew, . , Lafolet, . , Mahabiersing, . , Calhorda, . , Chardon-Noblat, . , Haukka, . , Deronzier, . (2009) Soluble redox-active polymetallic chains [{Ru-0(CO)(L)(bpy)}(m)](n) (bpy=2,2 '-bipyridine, L = PrCN, Cl-; m=0,-1): electrosynthesis and characterization . Inorganic Chemistry , 48 (17). pp. 8233-8244. ISSN: 0020-1669 | doi: http://dx.doi.org/10.1021/ic9008043
- Smith, . , Flynn, . , Fox, . , Trottier, . , Wrede, . , Yufit, . , Howard, . , Ronayne, . , Towrie, . , Parker, . , Hartl, . , Low, . (2008) Facile photoinduced charge separation through a cyanoacetylide bridge in a heterobimetallic Fe(II)-Re(I) complex. Chemical Communications (44). pp. 5845-5847. ISSN: 1359-7345 | doi: http://dx.doi.org/10.1039/b811357b
- Khairul, . , Albesa-Jové, . , Yufit, . , Al-Haddad, . , Collings, . , Hartl, . , Howard, . , Marder, . , Low, . (2008) The syntheses, structures and redox properties of phosphine-gold(I) and triruthenium-carbonyl cluster derivatives of tolans. Inorganica Chimica Acta , 361 (6). pp. 1646-1658. ISSN: 0020-1693 | doi: http://dx.doi.org/10.1016/j.ica.2007.03.032
- Jagesar, . , Hartl, . , Buma, . , Brouwer, . (2008) Infrared study of intercomponent interactions in a switchable hydrogen-bonded rotaxane. Chemistry- A European Journal , 14 (6). pp. 1935-1946. ISSN: 0947-6539 | doi: http://dx.doi.org/10.1002/chem.200701531
- Fox, . , Roberts, . , Baines, . , Le Guennic, . , Halet, . , Hartl, . , Yufit, . , Albesa- Jové, . , Howard, . , Low, . (2008) Ruthenium complexes of C,C '-bis(ethynyl)carboranes: an investigation of electronic interactions mediated by spherical pseudo-aromatic spacers. Journal of the American Chemical Society , 130 (11). pp. 3566-3578. ISSN: 0002-7863 | doi: http://dx.doi.org/10.1021/ja0779755
- Busby, . , Hartl, . , Matousek, . , Towrie, . , Vlček, . (2008) Ultrafast excited state dynamics controlling photochemical isomerization of N-methyl-4-[trans-2-(4-pyridyl)ethenyl]pyridinium coordinated to a {Re-1(CO)(3)(2,2 '-bipyridine)} chromophore. Chemistry- A European Journal , 14 (23). pp. 6912-6923. ISSN: 0947-6539 | doi: http://dx.doi.org/10.1002/chem.200800188
- Armitt, . , Bruce, . , Gaudio, . , Zaitseva, . , Skelton, . , White, . , Le Guennic, . , Halet, . , Fox, . , Roberts, . , Hartl, . , Low, . (2008) Some transition metal complexes derived from mono- and di-ethynyl perfluorobenzenes. Dalton Transactions (47). pp. 6763-6775. ISSN: 1364-5447 | doi: http://dx.doi.org/10.1039/b808798a
- Górski, M. , Hartl, F. , Szymańska-Buzar, T. (2007) Isomeric olefin tetracarbonyl complexes of tungsten(I): an infrared spectroelectrochemical study at low temperatures. Organometallics , 26 (16). pp. 4066-4071. ISSN: 1520-6041 | doi: http://dx.doi.org/10.1021/om700384g
- Gagliardo, M. , Amijs, C. , Lutz, M. , Spek, A. , Havenith, R. , Hartl, F. , van Klink, G. , van Koten, G. (2007) Diorganoruthenium complexes incorporating noninnocent [C6H2(CH2ER2)2-3,5]22-(E = N, P) Bis-Pincer bridging ligands: synthesis, spectroelectrochemistry, and DFT studies. Inorganic Chemistry , 46 (26). pp. 11133-11144. ISSN: 0020-1669 | doi: http://dx.doi.org/10.1021/ic701501q
- Fox, M. , Roberts, R. , Khairul, W. , Hartl, F. , Low, P. (2007) Spectroscopic properties and electronic structures of 17-electron half-sandwich ruthenium acetylide complexes, [Ru(CCAr)(L2)Cp′]+ (Ar=phenyl, p-tolyl, 1-naphthyl, 9-anthryl; L2=(PPh3)2, Cp′=Cp; L2=dppe; Cp′=Cp∗). Journal of Organometallic Chemistry , 692 (15). pp. 3277-3290. ISSN: 0022-328X | doi: http://dx.doi.org/10.1016/j.jorganchem.2007.03.042
- Benisvy, L. , Kannappan, R. , Song, Y. , Milikisyants, S. , Huber, M. , Mutikainen, I. , Turpeinen, U. , Gamez, P. , Bernasconi, L. , Baerends, E. , Hartl, F. , Reedijk, J. (2007) A square-planar nickel(II) monoradical complex with a bis(salicylidene)diamine ligand. European Journal of Inorganic Chemistry , 2007 (5). pp. 637-642. ISSN: 1434-1948 | doi: http://dx.doi.org/10.1002/ejic.200601015
- Gagliardo, M. , Perelaer, J. , Hartl, F. , van Klink, G. , van Koten, G. (2007) Mono- and heterodimetallic FeII and RuII complexes based on a novel heteroditopic 4′-{bis(phosphanyl)aryl}-2,2′:6′,2″-terpyridine ligand. European Journal of Inorganic Chemistry , 2007 (15). pp. 2111-2120. ISSN: 1434-1948 | doi: http://dx.doi.org/10.1002/ejic.200600928
- Hartl, F. , Rosa, P. , Ricard, L. , Lefloch, P. , Zalis, S. (2007) Electronic transitions and bonding properties in a series of five-coordinate “16-electron” complexes [Mn(CO)3(L2)]− (L2=chelating redox-active π-donor ligand). Coordination Chemistry Reviews , 251 (3-4). pp. 557-576. ISSN: 0010-8545 | doi: http://dx.doi.org/10.1016/j.ccr.2006.09.003
- Smith, M. , Cordiner, R. , Albesa-Jové, D. , Yufit, D. , Hartl, F. , Howard, J. , Low, P. (2006) The synthesis, structure, and electrochemical properties of Fe(C CC N)(dppe)Cp and related compounds. Canadian Journal of Chemistry , 84 (2). pp. 154-163. ISSN: 1480-3291 | doi: http://dx.doi.org/10.1139/v05-238
- Hartl, F. and van Outersterp, J. (2006) Multistep electrochemical reduction path of clusters [Os3(CO)10(α-diimine)]: comparison of electrochemical and photochemical Os-Os(α-diimine) bond cleavage. Collection of Czechoslovak Chemical Communications , 71 (2). pp. 237-263. ISSN: 0010-0765 | doi: http://dx.doi.org/10.1135/cccc20060237
- Durán Pachón, L. , Thathagar, M. , Hartl, F. , Rothenberg, G. (2006) Palladium-coated nickel nanoclusters: new Hiyama cross-coupling catalysts. Physical Chemistry Chemical Physics , 8 (1). pp. 151-157. ISSN: 1463-9076 | doi: http://dx.doi.org/10.1039/B513587G
- Hennig, H. , Schumer, F. , Reinhold, J. , Kaden, H. , Oelssner, W. , Schroth, W. , Spitzner, R. , Hartl, F. (2006) Molecular structures and electronic transitions of 3,6-Diphenyl-1,2-dithiin and its radical cation: a spectroelectrochemical and DFT study. The Journal of Physical Chemistry A , 110 (5). pp. 2039-2044. ISSN: 1089-5639 | doi: http://dx.doi.org/10.1021/jp0551059
- Gabrielsson, A. , Hartl, F. , Zhang, H. , Lindsay Smith, J. , Towrie, M. , Vlček, A. , Perutz, R. (2006) Ultrafast charge separation in a photoreactive rhenium-appended porphyrin assembly monitored by picosecond transient infrared spectroscopy. Journal of the American Chemical Society , 128 (13). pp. 4253-4266. ISSN: 0002-7863 | doi: http://dx.doi.org/10.1021/ja0539802
- Jukes, R. , Bozic, B. , Hartl, F. , Belser, P. , De Cola, L. (2006) Synthesis, photophysical, photochemical, and redox properties of nitrospiropyrans substituted with Ru or Os tris(bipyridine) complexes. Inorganic Chemistry , 45 (20). pp. 8326-8341. ISSN: 0020-1669 | doi: http://dx.doi.org/10.1021/ic0606680
- Gagliardo, M. , Rodríguez, G. , Dam, H. , Lutz, M. , Spek, A. , Havenith, R. , Coppo, P. , De Cola, L. , Hartl, F. , van Klink, G. , van Koten, G. (2006) A novel heteroditopic terpyridine-pincer ligand as building block for mono- and heterometallic Pd(II) and Ru(II) complexes. Inorganic Chemistry , 45 (5). pp. 2143-2155. ISSN: 0020-1669 | doi: http://dx.doi.org/10.1021/ic051967c
- Browne, W. , Ligtenbarg, A. , de Boer, J. , van den Berg, T. , Lutz, M. , Spek, A. , Hartl, F. , Hage, R. , Feringa, B. (2006) Electronic properties, redox behavior, and interactions with H2O2 of pH-sensitive hydroxyphenyl-1,2,4-triazole-based oxovanadium(V)complexes. Inorganic Chemistry , 45 (7). pp. 2903-2916. ISSN: 0020-1669 | doi: http://dx.doi.org/10.1021/ic051848x
- Cordiner, R. , Smith, M. , Batsanov, A. , Albesajove, D. , Hartl, F. , Howard, J. , Low, P. (2006) The synthesis, structure, reactivity and electrochemical properties of ruthenium complexes featuring cyanoacetylide ligands. Inorganica Chimica Acta , 359 (3). pp. 946-961. ISSN: 0020-1693 | doi: http://dx.doi.org/10.1016/j.ica.2005.06.044
- Belser, P. , De Cola, L. , Hartl, F. , Adamo, V. , Bozic, B. , Chriqui, Y. , Iyer, V. , Jukes, R. , Kühni, J. , Querol, M. , Roma, S. , Salluce, N. (2006) Photochromic switches incorporated in bridging ligands: a new tool to modulate energy-transfer processes. Advanced Functional Materials , 16 (2). pp. 195-208. ISSN: 1616-3028 | doi: http://dx.doi.org/10.1002/adfm.200500247 (special issue 'Supramolecular functional materials')
- Hartl, F. , Vernier, S. , Belser, P. (2005) Luminescence of a new Ru(II) polypyridine complex controlled by a redox-responsive protonable anthra[1,10]phenanthrolinequinone. Collection of Czechoslovak Chemical Communications , 70 (11). pp. 1891-1908. ISSN: 0010-0765 | doi: http://dx.doi.org/10.1135/cccc20051891
- Bruce, M. , Low, P. , Hartl, F. , Humphrey, P. , de Montigny, F. , Jevric, M. , Lapinte, C. , Perkins, G. , Roberts, R. , Skelton, B. , White, A. (2005) Syntheses, structures, some reactions, and electrochemical oxidation of ferrocenylethynyl complexes of iron, ruthenium, and osmium. Organometallics , 24 (22). pp. 5241-5255. ISSN: 1520-6041 | doi: http://dx.doi.org/10.1021/om050483l
- Gagliardo, M. , Chase, P. , Lutz, M. , Spek, A. , Hartl, F. , Havenith, R. , van Klink, G. , van Koten, G. (2005) A ruthenium(II) complex stabilized by a highly fluorinated PCP pincer ligand. Organometallics , 24 (19). pp. 4553-4557. ISSN: 1520-6041 | doi: http://dx.doi.org/10.1021/om050422n
- Gabrielsson, A. , Matousek, P. , Towrie, M. , Hartl, F. , Záliš, S. , Vlcek, A. (2005) Excited states of nitro-polypyridine metal complexes and their ultrafast decay. Time-resolved IR absorption, spectroelectrochemistry, and TD-DFT calculations of fac-[Re(Cl)(CO)3(5-Nitro-1,10-phenanthroline)]. Journal of Physical Chemistry A , 109 (28). pp. 6147-6153. ISSN: 1089-5639 | doi: http://dx.doi.org/10.1021/jp051677h
- Doux, M. , Mézailles, N. , Ricard, L. , Le Floch, P. , Vaz, P. , Calhorda, M. , Mahabiersing, T. , Hartl, F. (2005) Syntheses, x-ray structures, photochemistry, redox properties, and DFT calculations of interconvertible fac- and mer-[Mn(SPS)(CO)3] isomers containing a flexible SPS-based pincer ligand. Inorganic Chemistry , 44 (25). pp. 9213-9224. ISSN: 0020-1669 | doi: http://dx.doi.org/10.1021/ic050774m
- Vergeer, F. , Kleverlaan, C. , Matousek, P. , Towrie, M. , Stufkens, D. , Hartl, F. (2005) Redox control of light-induced charge separation in a transition metal cluster: photochemistry of a methyl viologen-substituted [Os-3(CO)10(a-diimine)] cluster. Inorganic Chemistry , 44 (5). pp. 1319-1331. ISSN: 0020-1669 | doi: http://dx.doi.org/10.1021/ic049191n
- Calhorda, M. , Costa, P. , Hartl, F. , Vergeer, F. (2005) A new interpretation of the bonding properties and UV–vis spectra of [M3(CO)12] clusters (M = Ru, Os): a TD-DFT study. Comptes Rendus Chimie , 8 (9-10). pp. 1477-1486. ISSN: 1631-0748 | doi: http://dx.doi.org/10.1016/j.crci.2004.07.006 (special issue 'Green and sustainable chemistry')
- Jukes, R. , Adamo, V. , Hartl, F. , Belser, P. , De Cola, L. (2005) Electronic energy transfer in a dinuclear Ru/Os complex containing a photoresponsive dithienylethene derivative as bridging ligand. Coordination Chemistry Reviews , 249 (13-14). pp. 1327-1335. ISSN: 0010-8545 | doi: http://dx.doi.org/10.1016/j.ccr.2004.12.015
- Low, P. , Roberts, R. , Cordiner, R. , Hartl, F. (2005) Electrochemical studies of bi- and polymetallic complexes featuring acetylide based bridging ligands. Journal of Solid State Electrochemistry , 9 (11). pp. 717-731. ISSN: 1433-0768 | doi: http://dx.doi.org/10.1007/s10008-005-0693-3
- Vergeer, F. , Lutz, M. , Spek, A. , Calhorda, M. , Stufkens, D. , Hartl, F. (2005) Heterosite effects in novel heteronuclear clusters [OS2Ru(CO)(11)(PPh3)] and Os2Ru(CO)(10)(2-acetylpyridine-N-isopropylimine)]. European Journal of Inorganic Chemistry , 2005 (11). pp. 2206-2222. ISSN: 1434-1948 | doi: http://dx.doi.org/10.1002/ejic.200401040
- Vergeer, F. , Mahabiersing, T. , Lozano, E. , Suss-Fink, G. , Hartl, F. (2004) Electrochemical and photochemical conversion of [Ru3Ir(mu(3)-H)(CO)(13)] into [Ru3Ir(mu-H)(3)(CO)(12)]. Journal of Cluster Science , 15 (1). pp. 47-59. ISSN: 1572-8862 | doi: http://dx.doi.org/10.1023/B:JOCL.0000021252.65477.bc
- Busby, M. , Matousek, P. , Towrie, M. , Clark, I. , Motevalli, M. , Hartl, F. , Vlček, A. (2004) Rhenium-to-benzoylpyridine and rhenium-to-bipyridine MLCT excited states offac-[Re(Cl)(4-benzoylpyridine)2(CO)3] andfac-[Re(4-benzoylpyridine)(CO)3(bpy)]+: a time-resolved spectroscopic and spectroelectrochemical study. Inorganic Chemistry , 43 (14). pp. 4523-4530. ISSN: 0020-1669 | doi: http://dx.doi.org/10.1021/ic049659m
- Hartl, F. , Mahabiersing, T. , Chardon-Noblat, S. , Da Costa, P. , Deronzier, A. (2004) Redox-active polymers based on nonbridged metal−metal bonds. Electrochemical formation of [Os(bpy)(CO)(L)]n(bpy = 2,2‘-bipyridine; L = CO, MeCN) and of their reduced forms: a spectroelectrochemical study. Inorganic Chemistry , 43 (22). pp. 7250-7258. ISSN: 0020-1669 | doi: http://dx.doi.org/10.1021/ic049216i
- Jukes, R. , Adamo, V. , Hartl, F. , Belser, P. , De Cola, L. (2004) Photochromic dithienylethene derivatives containing Ru(II) or Os(II) metal units. Sensitized photocyclization from a triplet state. Inorganic Chemistry , 43 (9). pp. 2779-2792. ISSN: 0020-1669 | doi: http://dx.doi.org/10.1021/ic035334e
- de Pater, B. , Frühauf, H. , Vrieze, K. , de Gelder, R. , Baerends, E. , McCormack, D. , Lutz, M. , Spek, A. , Hartl, F. (2004) Strongly nucleophilic RhI centre in square-planar complexes with terdentate (κ3) 2,2′:6′,2′′-terpyridine ligands: crystallographic, electrochemical and density functional theoretical studies. European Journal of Inorganic Chemistry , 2004 (8). pp. 1675-1686. ISSN: 1099-0682 | doi: http://dx.doi.org/10.1002/ejic.200300699
- Vergeer, F. , Matousek, P. , Towrie, M. , Costa, P. , Calhorda, M. , Hartl, F. (2004) Low-lying excited states and primary photoproducts of [Os-3(CO)(10)-(s-cis-L)] (L = cyclohexa-1,3-diene, buta-1,3-diene)] clusters studied by picosecond time-resolved UV/Vis and IR spectroscopy and by density functional theory. Chemistry- A European Journal , 10 (14). pp. 3451-3460. ISSN: 1521-3765 | doi: http://dx.doi.org/10.1002/chem.200400086
- Staffilani, M. , Höss, E. , Giesen, U. , Schneider, E. , Hartl, F. , Josel, H. , De Cola, L. (2003) Multimetallic ruthenium(II) complexes as electrochemiluminescent labels. Inorganic Chemistry , 42 (24). pp. 7789-7798. ISSN: 0020-1669 | doi: http://dx.doi.org/10.1021/ic034435+
- Mahabiersing, T. , Luyten, H. , Nieuwendam, R. , Hartl, F. (2003) Synthesis, spectroscopy and spectroelectrochemistry of chlorocarbonyl {1,2-bis[(2,6-diisopropylphenyl)imino]-acenaphthene-kappa(2)-N,N '}rhodium (I). Collection of Czechoslovak Chemical Communications , 68 (9). pp. 1687-1709. ISSN: 0010-0765 | doi: http://dx.doi.org/10.1135/cccc20031687
- Hartl, F. , Mahabiersing, T. , Le Floch, P. , Mathey, F. , Ricard, L. , Rosa, P. , Záliš, S. (2003) Electronic properties of 4,4 ',5,5 '-tetramethyl-2,2 '-biphosphinine (tmbp) in the redox series fac-[Mn(Br)(CO)(3)(tmbp)], [Mn(CO)(3)(tmbp)](2), and [Mn(CO)(3)(tmbp)](-): crystallographic, spectroelectrochemical, and DFT computational study. Inorganic Chemistry , 42 (14). pp. 4442-4455. ISSN: 0020-1669 | doi: http://dx.doi.org/10.1021/ic0206894
- Boomgaard , R. , Schier, H. , Kirchner, E. , Klaasen, R. , Hartl, F. , Van Der Leeuw, R. , Bakkeren, F. (2003) Oxidatively drying coating composition. | doi: WO 03/029371 A1
- Vergeer, F. , Calhorda, M. , Matousek, P. , Towrie, M. , Hartl, F. (2003) Marked influence of the bridging carbonyl ligands on the photo- and electrochemistry of the clusters [Ru-3(CO)(8)(mu-CO)(2)-(alpha-diimine)] (alpha-diimine = 2,2 '-bipyridine, 4,4 '-dimethyl-2,2 '-bipyridine and 2,2 '-bipyrimidine). Dalton Transactions (21). pp. 4084-4099. ISSN: 1364-5447 | doi: http://dx.doi.org/10.1039/b303437b