Professor Geoffrey Mitchell
Telephone + 44 (0)118 378 8573
Email g.r.mitchell@reading.ac.uk
Location Room 242
Professor Mitchell is also Director of the
Centre for Advanced Microscopy
and the Director of Research for the
School of Mathematics, Meteorology and Physics
My research focuses on polymer physics and smart materials. Much of the work
is centered on the molecular organisation of polymers including
liquid crystal and crystalline systems and how such organisation is influenced and controlled by
external fields such as electric, magnetic, extensional, shear and light. In
parallel, there is strong programme on smart materials underpinned by a
molecular understanding of the novel materials involved. Much of this work is
performed within the scope of the Polymer
Science Centre at Reading, an interschool activity involving both the School
of Mathematics, Meteorology and Physics and the School of Chemistry, Food
Biosciences and Pharmacy.
and the wider Nanoscience and
Materials Theme. Collaborative programmes also are in place with the
Centre for Biomimetics, the
School of Food Biosciences.,
Mathematics and the School of
Biological Sciences.
There are strong international collaborative research programmes including
with the University of Naples (Italy), the Rapid Prototyping Group at the
Instituto
Politιcnico de Leiria (Portugal),
The Biomedical Polymer Group Chiang
Mai University (Thailand) and within the UK with the University of Southampton
and the University of Oxford.
The smart materials programme involves the development of novel materials which
exhibit "intelligent" properties, for example the material can sense
environmental changes and adapt by modifying its properties. A major strand
involves liquid crystal elastomers. Liquid crystal elastomers are a fascinating
new class of materials which combine an entropically driven network structure
and the long range orientational ordering of the liquid crystal phase. The
interaction between these two competing effects gives rise to materials with new
phenomena which includes electrically induced shapes changes, mechanically
induced director reorientation, piezoelectric effects and much more. A major
current programme involves the development of novel actuator systems. We have
discovered a new technology in the form of soft-imprinting and applied this to
chiral structures with links to the life sciences. We have developed a new class
of elastomers namely, ferrronematic and we are currently exploring their use
across several applications as well as the basic physics involved. In addition
to liquid crystal gels we have a major programme in the development of smart
gels for vibrational damping.
The electronic and photonic properties of polymer based materials continues to
receive much attention. A major interest is the exploitation of polymeric
materials in supercapacitors. Supercapacitors are an essential technology for
both electric vehicles and other hybrid power systems especially within the
context of sustainable technologies. A variety of programmes exploit the
non-linear optical properties of organic polymers and most recently work has
focused on photorefractive polymers and photorefractive liquid crystal systems.
We have discovered and developed the technique of photo-induced poling which
allows patterns of non-linear optical activity to be written into thin polymer
films. This gives rise to new devices including both modulators and waveguide
systems.
Much of the focus of my research is the use of x-ray and neutron scattering
techniques to explore the molecular organisation of polymers and how that
molecular organisation can be modified by external fields. A major programme
involves time-resolving x-ray and neutron scattering studies of polymers in flow
fields (shear and extensional). Currently we are applying these techniques
coupled with novel in-situ deformation stages to the study of crystallisation of
polymers such as polyethylene and polypropylene from sheared melts and to the
behaviour of additives such as nucleating agents during flow. This work is
complemented by optical studies including light scattering and Raman microscopy.
A collaborative programme has developed with the School of Food Biosciences
which focuses on the study of elastic proteins and in particular gluten networks
within wheat dough. Here the emphasis is on biaxial extensional flow. We have
developed new broad Q neutron scattering techniques coupled tightly to molecular
modelling procedures which allow us to obtain detailed and realistic structures
for even complex polymer systems. At present the focus of much of the work is an
examination of the local interactions which stabilise miscible blends.
Each of these programmes involves the use of major international facilities for
example neutron scattering experiments are performed at ISIS (UK), ILL (France)
and at Studvisk (Sweden) while synchrotron-based x-ray scattering measurements
are made at the Daresbury SRS and at LURE, ESRF and DESY. These are complemented
by extensive in-house facilities.
Research Programmes
Smart Materials
Nano Structured Polymers
Nano Polymer Composites
Elastic Conducting Composites
Nanoporus polymers for supercapacitors
Polymer Crystallisation
Electrospun Fibres
Reaction Injection Moulding
Biomedical Polymers
Property Development in Biodegradable
Polymers
Photonic Band Gap Polymers
Solvent Induced Crystallisation
Novel Optical Security Devices
Publications
Publication List (pdf)
|