CH2PH1-Further Physical Chemistry

Module Provider: Chemistry
Number of credits: 20 [10 ECTS credits]
Terms in which taught: Autumn / Summer term module
Pre-requisites: CH1PH1 Physical Processes and Molecular Organisation
Non-modular pre-requisites:
Modules excluded:
Module version for: 2016/7

Module Convenor: Dr David Nutt


Summary module description:

The aim of this module is to further students’ understanding of key aspects of physical chemistry related to equilibrium and structure.

Assessable learning outcomes:
Students should be able to:
• Describe and discuss the subject matter of the module, and explain the concepts raised.
• Critically examine questions raised in tutorials and workshops, and analyse numerical problems on relevant material.

Additional outcomes:
The students should improve their numeracy and analytical skills through problem solving, and oral and presentational skills through tutorials.

Outline content:
J M Elliott (5) Electrochemistry
Aqueous electrolyte solutions: activity coefficients and Debye Huckel theory. Electrochemical cells. Thermodynamic parameters from emf measurements. pH and potentiometric titrations.

D Nutt (5) Spectroscopy
Absorption and scattering processes; Transition dipole moments; Selection rules; Rotational spectroscopy, vibrational spectroscopy and vibration-rotation spectroscopy of diatomic molecules; Raman spectroscopy; Vibronic spectroscopy.

C Pfrang (5) Introduction to Atmospheric Chemistry
Physical state/structure of the troposphere and stratosphere - pressure (hydrostatic balance), temperature (thermal equilibrium and the natural greenhouse effect, lapse rates) and static stability; General features of natural (and perturbed) tropospheric and stratospheric chemistry.

A M Squires (5) Kinetics
Multi-step kinetics: Steady-state approximation; Chain reactions - steady-state; Hydrogen/bromine; Branched chain reactions; Explosions; Hydrogen/oxygen. Techniques in Chemical Kinetic analysis: Stopped and Continuous Flow; Flash Photolysis; Lasers.

I W Hamley (4) Surface and Interface Physical Chemistry
Surface and Interfacial tension, surfactancy, Gibbs adsorption isotherm, micellization and surface activity, critical micelle concentration as equilibrium, considering associated thermodynamics, lyotropic liquid crystal phases of surfactants.

R Bennett (5) Statistical thermodynamics
Boltzmann Law, partition functions, thermodynamic functions, ideal monatomic and diatomic gases.

D Nutt (2 workshops) Maths for Physical Chemists.

Brief description of teaching and learning methods:
Approximately three one-hour lectures per week with tutorials and workshops on related material and on the underlying mathematical principles. 6 x 1-hour drop-in sessions.

Contact hours:
  Autumn Spring Summer
Lectures 29
Tutorials 2
Supervised time in studio/workshop 12 6
Guided independent study 151
Total hours by term 194.00 6.00
Total hours for module 200.00

Summative Assessment Methods:
Method Percentage
Written exam 80
Set exercise 20

Other information on summative assessment:
Coursework 20%
Tutorials (written work and oral contribution) 20%
Students attend tutorials and workshop/seminars on the material covered in this module. Attendance is compulsory at both. Tutorials are assessed on both the written work and oral contribution.

Tutorials must be submitted by the dates specified according to the tutorial grid on the Blackboard site.

Examination 80%

Formative assessment methods:
6 x workshops on problems of the type encountered in tutorials and examinations.
6 x drop-in sessions.

Penalties for late submission:

For students on chemistry-based degree courses any unexplained absence from more than two tutorials in chemistry will automatically incur a formal warning from the Department Director of Teaching and Learning.
The Module Convenor will apply the following penalties for work submitted late, in accordance with the University policy.
  • where the piece of work is submitted up to one calendar week after the original deadline (or any formally agreed extension to the deadline): 10% of the total marks available for the piece of work will be deducted from the mark for each working day (or part thereof) following the deadline up to a total of five working days;
  • where the piece of work is submitted more than five working days after the original deadline (or any formally agreed extension to the deadline): a mark of zero will be recorded.

  • The University policy statement on penalties for late submission can be found at:
    You are strongly advised to ensure that coursework is submitted by the relevant deadline. You should note that it is advisable to submit work in an unfinished state rather than to fail to submit any work.

    Length of examination:
    2 hours

    Requirements for a pass:
    A mark of 40% overall.

    Reassessment arrangements:
    Reassessment will be held in August and will be by examination only worth 100%.

    Additional Costs (specified where applicable):
    1) Required text books: Required text books:
    •'Chemistry' by Catherine E. Houscroft and Edwin C. Constable. ISBN-10: 0273733087, £70
    •'Atkins Physical Chemistry’ by Peter Atkins and Julio de Paula (10th edition). ISBN-10: 019969740X, ~£45
    •Chemistry Data Book, 2nd Edition in SI, by JG Stark and HG Wallace. ISBN-10: 071953951X, £18.99

    2) Specialist equipment or materials: Scientific Calculator (non-programmable), £10.00
    3) Specialist clothing, footwear or headgear:
    4) Printing and binding:
    5) Computers and devices with a particular specification:
    6) Travel, accommodation and subsistence:

    Last updated: 21 December 2016

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